Export efficiency of black carbon aerosol in continental outflow: global implications
We use aircraft observations of Asian outflow from the NASA TRACE-P mission over the NW Pacific
in March-April, 2001 to quantify the export efficiency of black carbon (BC) aerosol during lifting
to the free troposphere, as limited by scavenging from the wet processes (warm conveyor belts, convection)
associated with this lifting.
Our estimate is based on the enhancement ratio of BC relative to CO in Asian
outflow observed at different altitudes, and normalized to the enhancement ratio observed in boundary layer
outflow (0-1 km). We similarly estimate export efficiencies of sulfur oxides (SOx = SO2(g)
+ SO42-) and total
inorganic nitrate (HNO3T = HNO3(g) + NO3-) for comparison to BC. Figure shows mean vertical profiles of
export efficiency (left) and normalized export efficiency (right) in Asian outflow for BC (squares),
SOx (diamonds), and HNO3T (asterisks).
Normalized export efficiencies for BC are
0.63 - 0.74 at 2 - 4 km altitude and 0.27 - 0.38 at 4 - 6 km. Values are higher than for SOx (0.48 - 0.66)
and HNO3T (0.29 - 0.62), at least at 2 - 4 km, implying that BC is scavenged in wet updrafts but not to the
extent of sulfate or nitrate. Simulation of the TRACE-P period with a global 3-D model (GEOS-CHEM) indicates
that a model time scale of 1±1 days for conversion of fresh hydrophobic to hydrophilic BC provides
a successful fit to the export efficiencies observed in TRACE-P. The resulting mean atmospheric lifetime of
BC is 5.8±1.8 days, the global burden is 0.11±0.03 Tg C, and the decrease in Arctic snow albedo due to
BC deposition is 3.1±2.5%. To learn more, click here:
[Park et al., 2004]
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